This is a link to the France railways site:
http://www.voyages-sncf.com/dynamic/_SvHomePage?_DLG=SvHomePage&_CMD=cmdHomepageUK&WB= HP&rfrr=4685ac17fd2e7656e4918c53b246a3f7
Here is a link to the Italian Railways website: http://www.trenitalia.com/en/index.html
Both are in English.
If you enter Paris and Rome, select the day you want to travel and either an time early in the morning for a day train, or a time early evening for an overnight train, you get times.
Some tickets are sold on internet, in that case these sites can sell them to you, if not, you will have to go to a travel agency, or to a railway station.
Railway stations in Europe often sell tickets for all other European railways, but not always, but it is worth the try if you are already somewhere in Europe. Paris the main stations are your best bet.
The Italian site seemed to sell more of the tickets for this trip, but maybe that is because with several journeys you will have to change in Italy.
There are also through trains.
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