Something to add to what others have already said:
1. Chernobyl. It was a big one. It demolished Russia's industrial prestige and destabilized the central part of the country.
2. Increasing erosion of responsibility. That's the PSYCHOLOGICAL effect of living in a totalitarian communist state -- where "ze government" is responsible for everything, no individual is responsible for anything. Little by little, generation by generation, government functionaries from top to bottom just stopped, well, functioning.
3. The demise of agriculture and farming. This began with collectivization in the 1930's and was accelerated by Kruschev inane agricultural policies in the 1960's. The system of collective farms turned rural residents into virtual slaves, whose right to travel, move, etc. was even more severely restricted than that of urban domiciliaries. At the same time, poverty in the rural areas was indescribable. People, consequently, sought to escape in any way they could. Young people particularly, high school graduates, left in droves, turning themselves inside out to get into college, signing up to go to the Arctic -- anything to escape the village. By the mid-1980's, the Russian countryside was pretty much deserted, and the only people left were mostly very old. The result? A country with the largest land mass in the world, most of it very fertile, became unable to feed itself. The USSR, which could have been, literally, the world's bread basket, was buying grain abroad since the 1960's, and the purchases were growing at staggering rates throughout the following next decades. Even today, agriculture in Russia is virtually non-existent.
4. Ronald Reagan. Seriously. The man was a genius, even when he had Alzheimer's. As someone who lived in the USSR in the 1980's, let me assure you: the USSR really believed that the "Star Wars" thing was the real deal. Seriously. (Reagan's mind may have been slipping, but the string of GenSec's the Soviet Union had in that decade was more so by several orders of magnitude.) Naturally, when you are a leader and you think your enemy is in the process of contructing a Death Star in outer space and cloning a Darth Vader, your priorities are going to change. The USSR spent INSANE amounts of money on its military in the 1980's -- INSANE. Most of it on stockpiling nukes. Those INSANE expenditures is what broke the camel's back.
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